Formation of saline groundwaters in the Baltic region through freezing of seawater during glacial periods

Typical Ca---Cl brines occur in crystalline and metamorphic rocks below freshwater horizons at various localities in Sweden and Finland. Total dissolved solids (TDS) range in concentration between 2 and 120 gl⁻¹ and have long been thought to derive from water-rock interactions. The relationships between Na, Cl and Br in these brines suggest, however, that they were derived from freezing of seawater during glacial periods. The brines were subsequently diluted by meteoric waters and their Ca/Mg ratio was increased through water-rock interactions in the subsurface. The hydrogeological model for both the formation of freeze-derived marine brines and their lateral intrusion involves restricted inland marine basins in recent and subrecent polar climatic belts. Seawater in such basins gradually freezes in response to glaciation. The solutes which concentrate in the remaining water body are residual after precipitation of a sequence of minerals which include carbonates, mirabilite and hydrohalite. Hydraulic pressure of the growing ice sheet over the frozen seas is gradually added to the ambient hydrostatic pressure exerted on the brines. This, together with their increased density, increases the intrusional potential of the brines. As the land ice cannot exert hydraulic pressure on continental groundwater in the aquifers, the balance of pressure favours deep landward intrusion of brines. Post-glacial processes cause the subsurface dilution and replacement of the brines both by seawater and fresh waters. The presence of such brines also far from present-day coastal settings reflects the shifting of coastlines as a result of isostatic movements and eustatic sea-level changes associated with glaciation and deglaciation.