Wet season hydrochemistry of Bribin Cave in Gunung Sewu Karst, Indonesia

This research was conducted on the Bribin River, the most important underground river in the Gunung Sewu Karst, Gunung Kidul, Java, Indonesia. The main purpose of this study was to define the wet-season hydrochemistry of this river. This research also focuses on identifying the relationship between hydrochemical parameters to provide better aquifer characterization. Water-level monitoring and discharge measurements were conducted over a 1-year period to define the discharge hydrograph. Furthermore, baseflow-separation analysis is conducted to determine the diffuse-flow percentage throughout the year. Water sampling for hydrogeochemical analysis is taken every month in the wet season and every 2?hours for two selected flood events. To describe the hydrogeochemical processes, a bivariate plot analysis of certain hydrochemical parameters is conducted. The results show that the diffuse-flow percentage significantly controls the river hydrochemistry. The domination of diffuse flow occurs during non-flooding and flood recession periods, which are typified by a high value of calcium and bicarbonate and low CO₂ gas content in water. Conversely, the hydrochemistry of flood events is characterized by the domination of conduit flow and CO₂ gas with low calcium and bicarbonate content. According to the wet-season hydrochemistry, it seems that the small- and medium-sized fractures in the Bribin aquifer still provide storage for the diffuse and fissure flows, although the conduit fracture is already developed.