Ultra-calcic Magmas Generated from Ca-depleted Mantle: an Experimental Study on the Origin of Ankaramites |
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Authors: | SCHMIDT, MAX W. GREEN, DAVID H. HIBBERSON, WILLIAM O. |
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Affiliation: | 1 INSTITUTE OF MINERALOGY AND PETROLOGY, ETH ZURICH, 8092 ZURICH, SWITZERLAND 2 RESEARCH SCHOOL OF EARTH SCIENCES, ANU, CANBERRA, A.C.T. 0200, AUSTRALIA |
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Abstract: | Ultra-calcic ankaramitic magmas or melt inclusions are ubiquitousin arc, ocean-island and mid-ocean ridge settings. They areprimitive in character (XMg > 0·65) and have highCaO contents (>14 wt %) and CaO/Al2O3 (>1·1). Experimentson an ankaramite from Epi, Vanuatu arc, demonstrate that itsliquidus surface has only clinopyroxene at pressures of 15 and20 kbar, with XCO2 in the volatile component from 0 to 0·86.The parental Epi ankaramite is thus not an unfractionated magma.However, forcing the ankaramite experimentally into saturationwith olivine, orthopyroxene and spinel results in more magnesian,ultra-calcic melts with CaO/Al2O3 of 1·211·58.The experimental melts are not extremely Ca-rich but high inCaO/Al2O3 and in MgO (up to 18.5 wt %), and would evolve tohigh-CaO melts through olivine fractionation. Fractionationmodels show that the Epi parent magma can be derived from suchultra-calcic experimental melts through mainly olivine fractionation.We show that the experimental ultra-calcic melts could formthrough low-degree melting of somewhat refractory mantle. Thelatter would have been depleted by previous melt extraction,which increases the CaO/Al2O3 in the residue as long as someclinopyroxene remains residual. This finding corrects the commonassumption that ultra-calcic magmas must come from a Ca-richpyroxenite-type source. The temperatures necessary for the generationof ultra-calcic magmas are |
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Keywords: | : ankaramite refractory lherzolite ultra-calcic magma |
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