| Abstract: | Reversible mass transfer associated with alteration of carbonate rocks can be modeled in terms of a pore fluid migrating across a temperature field slowly enough that chemical equilibrium is maintained. These types of models yield both the spatial distribution of the alteration and the absolute amounts of minerals dissolved and precipitated. In order to compute the total mass transfer involved, it is necessary to obtain mass transfer coefficients for each mineral. This paper presents detailed examples of mass transfer in closed systems for the system calcite-dolomite-solution over the temperature range 0–200°C. It is shown that the mass transfer coefficients for the reversible process can be obtained from thermodynamic data and elementary solubility calculations. The connection between these reversible coefficients and the more familiar irreversible mass transfer coefficients is shown to be a simple derivative relation. Calculations are presented for two cases: calcite-ordered dolomite solution and calcite-disordered dolomite solution in both pure water and brines with Ca/Mg ratios similar to seawater. The large mass transfer coefficients obtained for the brines relative tot he pure water is attributed to the fact that the presence of both calcite and dolomite in a system fixes the Ca/Mg cation ratio in the solution as a function of temperature. Dolomitization occurring in nature likely involves both reversible and irreversible processes and accurate interpretation of field data requires the ability to distinguish between these two cases. |
