Dissolution and precipitation processes in deformed amphibolites: an example from the ductile shear zone of the Ryoke metamorphic belt, SW Japan

The granitic mylonite zone in the Cretaceous Ryoke metamorphic belt contains deformed amphibolites as thin layers. The amphibolite layers do not exhibit pinch‐and‐swell or boudinage structures, even when contained in a high‐strain granitic mylonite. This mode of occurrence suggests that they were deformed as much as the surrounding granite mylonite. In the highly deformed zone, strongly foliated amphibolites contain Ti‐rich brown amphibole porphyroclasts rimmed by Ti‐poor green amphibole, titanite and chlorite. These porphyroclasts are elongated, forming shear surfaces defined by preferential distribution of the chlorite and titanite. Porphyroclastic plagioclase in the strongly foliated amphibolites consists of two components: an anorthite‐rich core and an anorthite‐poor rim. Based on these observations, the mass‐balanced reaction occurring during deformation is defined as As the reaction products form a weak interconnected matrix, the strain rate of the amphibolites may be controlled by the rate of dissolution–precipitation through fluids. Weakly foliated amphibolites in the low‐strain zone exhibit cataclastic microstructures, whereas the strongly foliated amphibolites do not exhibit such features. These microstructural and chemical changes suggest that high‐strain amphibolites were initially deformed by cataclasis, followed by deformation through metamorphic reactions. During the metamorphism/deformation, old plagioclase grains with high X_an were not stable and dissolved, and new plagioclase grains with low X_an crystallized at the old plagioclase rim. Dissolution of old plagioclase and precipitation of new plagioclase occurred normal to and parallel to the foliation, respectively, reflecting incongruent pressure solution due to differential stress and changes in P–T–H₂O conditions. The development of incongruent pressure solution is attributed to increased fluid flux in the strongly foliated amphibolites, as evidenced by the greater abundance of hydration‐reaction products in the strongly foliated amphibolites than in the weakly foliated ones.