Fluorine contents of some hydrous minerals derived from upper mantle and lower crust

Fluorine contents have been determined in about forty samples of amphibole, mica and apatite in alkali basalt and kimberlite and their incorporated xenoliths. They show a wide variation ranging from 15,000 to 100 ppm, corresponding to about 40 to 0.2 per cent substitution of F for OH in hydroxyl site of hydrous minerals. Fluorine abundances in these minerals reflect those of their host magmas or rocks; Itinome-gata xenoliths are the lowest and South African kimberlites and their xenoliths are the highest. F/OH and also. D/H (Kuroda et al. 1975) ratios in coexisting phlogopite-potassic richterite from peridotite and mica nodules are thoughts to have formed under no simple equlibrium conditions.