Thermodynamics of phase transitions in the system ice VI-ice VII-water |
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Authors: | D V Antsyshkin A N Dunaeva O L Kuskov |
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Institution: | 1.Vernadsky Institute of Geochemistry and Analytical Chemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | The paper presents an analysis of experimental results on phase equilibria in the system ice VI-ice VII-water. The mathematical
processing of the experimental data makes it possible to further constrain the location of phase transition boundaries between
crystalline ices VI and VII and liquid water. Based on the standard thermodynamic properties of H2O, an equation was derived for the free energy of formation of liquid water in its stability fields. The equations thus obtained
were then utilized to calculate the standard thermodynamic properties (free energy, enthalpy, and entropy) of water ice VI
and VII and the free energy of their formation at pressures of 6.3–25 kbar. |
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