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辽吉内生硼矿硼镁铁矿──硼铁矿系列的矿物学研究
引用本文:黄作良,王培君,王濮.辽吉内生硼矿硼镁铁矿──硼铁矿系列的矿物学研究[J].化工矿产地质,1994(3).
作者姓名:黄作良  王培君  王濮
作者单位:化学工业部化学矿产地质研究院,中国地质大学
摘    要:辽吉内生硼矿分布于宽甸群的高小岭组(Pt1kn4)、老营沟组(Pt1kn6)和砖庙组(Pt1kn7)地层中。在硼矿床中,硼镁铁矿-硼铁矿系列的矿物有富镁硼铁矿、富铁硼镁铁矿和富镁硼镁铁矿。它们的矿物学特征取决于j值[FeO/(FeO+MgO)],f值增大,硼镁铁矿的反射色、反射多色性和偏光色明显;红外光谱则表现为ν2和ν4的振动频率低移;晶胞参数a0和c0增大。f值减小,颜色、多色性变化明显。从Pt1kn4→Pt1kn6→Pt1kn7,硼镁铁矿的f值逐渐减小,氧化系数增大,其形成向着富镁、氧化程度高的方向演化。硼镁铁矿的矿物学特征具有含硼层的指示意义。

关 键 词:内生硼矿床,硼镁铁矿-硼铁矿系列,矿物学特征

MINERALOGY OF LUDWIGITE-VONSENITE SERIES OF ENDOGENETIC BORATE DEPOSITS IN THE LIAONING-JILIN REGION
Abstract:Abstract In the paper,minerals of ludwigite-vonsenite series are studied for endogenetic borate deceits in Liaoning -Jilin Region.These minerals include rich-Mg vonsenite,rich-torn ludwigite and rich-Mg ludwigite.Their mineralogy characters depend on ratio between FeO and(FeO + MgO).When FeO/(FeO+ MgO) increase, reflecting colour,reflection pleo-chroism and polarization colour are apparent, the viberation frequences of υ2 and υ4 are decreased in infrared spectroscopy and the unit cell parameters(a,C0) are increased.From Gaoxiaoling formation (Pt1kn4) to (Pt1kn6)and to Zhuanmiao formation (Pt1kn7)of Kuandian Group,the FeO/(FeO+MgO) of ludwigite is decreased,but the oxidation ratio is increased,The formation of ludwigite is advance towards the direction of rich-Mg and oxidation evolution.
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