Molecular and low excitation emission in high mass post-main-sequence nebulae

We have undertaken mapping and spectroscopy of a broad range of type I post-Main-Sequence nebulae in COJ=1→0,J=2→1, andJ=3→2, using the 12 m antenna at Kitt Peak, and the 45 m facility of the Nobeyama Radio Observatory. As a consequence, we find COJ=2→1 emission associated with NGC 3132 and NGC 6445, determine the location of COJ=1→0 emission in the nucleus of NGC 6302, and obtain (for the first time) COJ=3→2 spectroscopy for a substantial cross-section of type I sources. LVG analysis of the results suggests densitiesn(H₂) ～ 10⁴ cm^?3, and velocity gradients dv/dr ～ 2×10² in both NGC 7027 and CRL 618, commensurate with uniform expansion of a constant velocity outflow, whilst for the case of NGC 2346 these values probably exceedn(H₂) ～ 4.0×10⁵ cm^?3. dv/dr ～ 2.6×10³ km s^?1 andT _k ～10² K, implying appreciable compression (and shock heating?) of the CO excitation zone. Hi masses extend over a typical range 0.01<M(Hi)/M _⊙<1, whilst corresponding estimates of the progenitor mass imply 0.7<M _prog/M _⊙<2.3; values significantly in excess of those pertinent for normal PN, although somewhat at the lower end of the type I mass range. COJ=3→2 profiles for CRL 2688 confirm the presence of an extended plateau with width Δv～85 km s^?1, whilst modestJ=3→2 enhancement is also observed for the high-velocity components in NGC 7027. TheJ=3→2 spectrum for NGC 2346 appears to mimic lower-frequency results reasonably closely, confirming the presence of a double-peaked structure towards the core, and predominantly unitary profiles to the north and south, whilst there is also evidence to suggest appreciableJ=3→2 asymmetry in CRL 618 compared to lower-frequency measures. The status of an extended cloud near HB 5 remains uncertain, although this clearly represents a remarkably complex region with velocity span ΔV～50 km s^?1. Our presentJ=3→2 results appear to track lower frequency measures extremely closely, implying local densitiesn(H₂)>3×10³ cm^?3—although temperatures close to theV _lsr of HB 5 are relatively weak, and of orderT _MB (J=3→2)≤0.9 K. Finally, as a result of both this, and previous investigations we find that of type I sources so far observed in CO, some ～42% appear to possess detectable levels of emissionT _r ^* >0.1 K. Similarly, in cross-correlating this data with other results, we note a closely linear relation betweenJ=2→1 antenna temperaturesT _MB, and the surface brightness of H₂ S(1) quadrupole emissionS(H₂)—a trend which appears also to be reflected betweenS(H₂) and corresponding parameters for Oi], Oii], Ni], Nii], and Sii]. Such relations almost certainly arise from comparable secular variations in line intensities, although the CO, H₂, and optical emission components are likely to derive from disparate line excitation zones. As a consequence, it is clear that whilst H₂ S(1) emission is probably enhanced as a result of local shock activity, the evidence for post-shock excitation of the CO and optical forbidden lines is at best marginal. Similarly, although it seems likely that CO emission derives from circum-nebular Hi shells with kinetic temperatureT _k ～ 30 K or greater, the predominant fraction of low-excitation emission arises from a mix of charge exchange reactions, nebular stratification and, probably most importantly, the influence of UV shadow zones and associated neutral inclusions.