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Surfactants in the sea-surface microlayer and their contribution to atmospheric aerosols around coastal areas of the Malaysian peninsula
Authors:Razarul Naim Roslan  Mohamed Rozali Othman  Xan Xue Yan  Che Abd Rahim Mohamed
Institution:a School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
b School of Environmental and Natural Resource Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
Abstract:A study was done to determine the concentrations of surfactants on the sea-surface microlayer and in atmospheric aerosols in several coastal areas around the Malaysian peninsula. The concentrations of surfactants from the sea-surface microlayer (collected using rotation drum) and from aerosols (collected using HVS) were analyzed as methylene blue active substances and disulphine blue active substances through the colorimetric method using a UV-vis spectrophotometer. The results of this study showed that the average concentrations of surfactants in the sea-surface microlayer ranged between undetected and 0.36 ± 0.34 μmol L−1 for MBAS and between 0.11 ± 0.02 and 0.21 ± 0.13 μmol L−1 for DBAS. The contribution of surfactants from the sea-surface microlayer to the composition of surfactants in atmospheric aerosols appears to be very minimal and more dominant in fine mode aerosols.
Keywords:Surfactants  Coastal area  Sea-surface microlayer  Atmospheric aerosol  MBAS  DBAS
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