Internal mechanism of metastable liquid water crystallization and its effects on intracloud processes

Specific features of an internal freezing (crystallization) mechanism for both ordinary supercooled water and amorphous water (A-water) are considered. Amorphous water plays the role of an intermediate phase in condensation ice formation and is capable of metastable existence in the form of cloud drops. It is demonstrated that, after passing the crystallization front, the ice phase takes the liquid-phase volume and the excessive water mass is detached from the front in the form of free molecules, which escape through the liquid into the gaseous medium. The released energy of the phase transition is removed with these molecules, so that the formed ice retains the initial temperature of the liquid. A high-rate vapor outflow from the freezing drop generates (around the drop) a zone of microscale turbulence, which accelerates the mass exchange between cloud particle and vapor. Since the freezing frequency of drops in a cloud increases with their size, the effects of their freezing develop initially in time. At the same time, these effects initiate such processes that end in a complete evaporation of supercooled water drops and in a sharp enlargement of A-water and ice particles, i.e., in cloud transition to such a phase-mixed state where the liquid disperse phase consists of A-water drops. A reduction in the duration of the initial (fine-dispersed) stage of the evolution of clouds with their temperature lowering can be explained only by the development of microscale disturbances as a result of the freezing of drops.