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The effects of dissolved organic matter on the aqueous partitioning of polynuclear aromatic hydrocarbons
Authors:Brian Whitehouse
Institution:Department of Oceanography, Dalhousie University, Halifax, N.S., Canada B3H 4J1
Abstract:The partitioning of six polynuclear aromatic hydrocarbons into aqueous solutions containing dissolved organic matter from various coastal environments was investigated by liquid chromatography. Specific hydrocarbon-organic matter interactions were observed. The greatest interactions occurred with the very low solubility hydrocarbons and with organic matter of terrestrial origin. Ultrafiltration experiments suggested that it was the relatively high (greater than approximately 500) molecular weight organic matter that was interacting with the hydrocarbons.
Keywords:dissolved organic compounds  hydrocarbons  liquid chromatography  molecular weight  Nova Scotia
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