Abstract: | The derivation of element abundances of stars is a key step in detailed spectroscopic analysis. A spectroscopic method may suffer from errors associated with model simplifications. We have developed a new method of deriving the various element abundances of stars based on the calibration established from a group of standard stars. We perform principal component analysis(PCA) on a homogeneous library of stellar spectra, and then use machine learning to calibrate the relationship between principal components and element abundances. By testing with spectral libraries S4 N and MILES, we find that our procedure provides good consistency when spectra from a homogeneous set of observations are used, and it could be expanded to stars with quite a wide range of stellar parameters, with both dwarfs and giants. Moreover, we discuss the four key factors that have a significant impact on the results of derived element abundances,including the resolution of the spectra, wavelength range, the signal-to-noise ratio(S/N) of spectra and the number of principal components adopted. |