Abstract: | In this paper, I develop global karst chemical denudation models using chemical equilibrium equations. Theoretical karst chemical denudation rates are calculated as soil carbon dioxide concentration varies from 10?3.5 atm to 10?1.0 atm, temperature varies from 0°C to 30°C, and annual runoff varies from 500 mm to 3,000 mm. Both open and closed karst solution systems are examined. The Drake (1980) and the Brook‐Folkoff‐Box (1983) soil pCO2 equations are used to develop chemical denudation models for different carbonate rocks (limestone and dolomite), climate (tropical, temperate, and arctic/alpine terrains), and karst solution type (open and closed systems). The major conclusion is that the karst solution type, least known in the past karst studies, is an important factor in controlling chemical denudation rates. |