Rare-earth element geochemistry of Madras granulites

Archaean granulites from the type charnockite locality of Pallavaram, Madras City, Tamil Nadu, southern India consist of a bimodal suite of basic and silicic orthogneisses, associated with metasedimentary gneisses (khondalites). Charnockite is the dominant rock type. Basic granulites display a tholeiitic trend of strong iron enrichment accompanied by an increase in the concentration of the rare earth elements (REE), and the development of appreciable negative europium anomalies. These trends are considered to reflect low pressure fractional crystallisation of pyroxene-plagioclase assemblages under conditions of lowf _{O 2}. Ultramafic granulites may represent the cumulus material of such a process. The silicic granulites (charnockites) are generally K₂O rich and in marked contrast to the low K₂O (tonalitic) silicic gneisses which dominate most granulite facies terrains. Their REE abundances, however, embrace the complete range of patterns observed in both K-rich and K-poor Archaean gneisses. The presence of a large number of pre-granulite facies potassic pegmatites in the area suggests metasomatism of an originally less potassic suite of rocks. Trace element considerations lead to a model whereby metasomatism and partial fusion of silicic gneisses in the terrain preceded the granulite facies metamorphic event. This sequence of events is best related to fluctuations in the composition of metamorphic fluids in the lower crust.