The dissociation of OH and OD in comets by solar radiation

The radiative lifetimes of cometary OH are calculated as a function of the heliocentric velocity of the comet and the velocity distributions of the product atoms are determined. At a distance of 1 AU from the Sun, the lifetimes vary between 1.2×10⁵ and 1.9×10⁵ sec at solar minimum and between 1.0×10⁵ and 1.4×10⁵ sec at solar maximum, depending upon velocity. Continuous absorption into the repulsive 1²Σ^- state is major destruction path. The calculated lifetimes are generally consistent with the lifetimes inferred from observations, but suggest some elaboration of the models is necessary. Photodissociation of OH produces a low-velocity component of hydrogen atoms at 8 km sec^?1 relative to the parent OH molecule and a high-velocity component between 17 and 27 km sec^?1. Photodissociation of OH leads to metastable O(¹D) and O(¹S) and is an additional source of the red and green line emission of atomic oxygen. The lifetime of OD is estimated to be about 4.3× 10⁵ sec at solar minimum and 2.6×10⁵ sec at solar maximum so that the OD/OH ratio in comets is enhanced relative to the HDO/H₂O production ratio by a factor between 2 and 3. Photodissociation of OD produces only high-velocity D atoms with a mean value of 17 km sec^?1.