The variability of chemical analyses as a function of sample heterogeneity,and the implications to the analyses of rock standards

The errors in the chemical analyses of a granodiorite rock powder for 6 constituents (K ₂O, Na₂O, CaO,∑Fe₂O₃, MgO, and MnO) have been determined by replicate analyses of the whole rock and of a series of different sieved fractions. Sample inhomogeneity is indicated. This is confirmed by analyses of the fused rock powder. Fusion to a glass is therefore recommended for the preparation of geochemical rock standards.