Closed system Fischer-Tropsch synthesis over meteoritic iron,iron ore and nickel-iron alloy |
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Authors: | DW Nooner JM Gibert E Gelpi |
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Institution: | Departments of Biophysical Sciences and Chemistry, University of Houston, Houston, Texas 77004, U.S.A. |
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Abstract: | Meteoritic iron, iron ore and nickel-iron alloy (either alone or in some cases mixed with alumina, carbonaceous chondrite, potassium carbonate or sodium carbonate) were used to catalyze the reaction of deuterium and carbon monoxide in a closed reaction vessel. The mole ratio of deuterium to carbon monoxide ranged from 1/2:1 to 10:1, the reaction temperature from 195 to 370°C, and the reaction time from 6 to 480 hr. Analysis of the reaction products showed that normal alkanes and alkenes (C11-C25), their monomethyl substituted isomers and aromatic hydrocarbons (e.g. naphthalene, acenaphthene, fluorene, phenanthrene and the methyl derivatives of these hydrocarbons) were synthesized. In addition to the aforementioned hydrocarbons, one reaction product was shown to contain perdeutero normal fatty acids (10:0–16:0). |
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Keywords: | To whom correspondence should be addressed |
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