Methane in the western North Pacific

The concentration of methane in about 400 seawater samples collected in the western North Pacific, mostly from 40°N to 5°S along 165°E was determined. While the concentration of methane in the surface water was slightly greater in the high-latitudes, it did not widely vary with a standard deviation of 0.29 n mol/l for a mean value of 2.49 n mol/l. The 90% confidence limit of the mean was 0.08 n mol/l. The degree of oversaturation in 1991 (31±4%) was not different from that in circa 1970. If we assume that this degree of oversaturation occurs in the entire oceans, the annual flux of methane becomes 6×10¹²g CH₄. Both the concentrations of methane and chlorophylla were higher in the surface 100 m layer. However, the correlation between them was not well in the entire surface waters. This may indicate that the production of methane is not directly related to the photosynthetic process. The concentration of methane decreased gradually with increasing depth down to 1000 m. Its horizontally and vertically uniform concentration in the abyssal water suggests that the turnover time of methane in the oxic pelagic water is in the range between a few years and a few hundred years.