Room-temperature compressibilities of MnO and CdO: further examination of the role of cation type in bulk modulus systematics |
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Authors: | Jianzhong Zhang |
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Institution: | (1) CHiPR and Department of Geosciences, State University of New York at Stony Brook, Stony Brook, 11794, U.S.A. e-mail: zhang@sbmp04.ess.sunysb.edu, US |
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Abstract: | Room-temperature volume measurements up to 8.1 GPa reveal that rock-salt structured MnO and CdO have identical compressibility
in the pressure range studied. In the plot of bulk modulus vs unit-cell volume, CdO plots well above the trend of the 3d transition
metal monoxides, a behavior that deviates from empirical predictions of constant K
0
V
0. The present observations are in favor of our earlier suggestion that, for isostructural solids, the empirically predicted
bulk modulus-volume relationship may be limited to their subsets that share the same valence electron character (i.e., s vs
3d vs 4d). For cations forming transition metal monoxides, variations of Pauling electronegativity with ionic radius show
differences that are qualitatively similar to the observed trends of bulk modulus, suggesting that bond covalency differences
may contribute to the different behaviors between the 3d and 4d transition metal monoxides.
Received: 23 November 1998 / Revised, accepted: 1 April 1999 |
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Keywords: | MnO CdO rock-salt monoxides X-ray diffraction equation of state |
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