Theoretical model for the formation of ion-pairs in seawater |
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| Authors: | Dana R Kester Ricardo M Pytkowicz |
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| Institution: | 1. Graduate School of Oceanography, University of Rhode Island, Kingston, R.I. U.S.A.;2. School of Oceanography, Oregon State University, Corvallis, Oreg. U.S.A. |
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| Abstract: | Predictions of association constants for ion-pair formation in seawater were compared to measured constants as a test for the existence of ion-pairs. A fair agreement was obtained in most cases, although the theoretical electrostatic calculations indicate that significant chloride ion-pairing should occur which has not been observed in most experimental investigations. |
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