Comparative organic petrology of interlayered sandstones,siltstones, mudstones and coals in the Upper Carboniferous Ruhr basin,Northwest Germany,and their thermal history and methane generation |
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Authors: | Dr Günter Scheidt Dr Ralf Littke |
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Institution: | (1) Present address: Harress Geotechnik GmbH, Steinmühlenweg 8, D-6093 Flörsheim;(2) Present address: Institut für Erdöl und Organische Geochemie (ICH-5), KFA Jülich GmbH, D-5170 Jülich |
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Abstract: | In the coal-mining Ruhr-area, Upper Carboniferous rocks (ca. 4000 m) consist of interlayered sandstones, siltstones, mudstones and coals. They were deposited in a tropical, paralic environment where alternating fluvial sedimentation, occasional marine ingressions, and swamp growth resulted in an irregular cyclic succession. The total sedimentary package contains on an average 6 Vol.-% of organic matter. About 70 Vol.-% of the organic matter occurs in coal seams, the rest as dispersed organic matter in clastic rocks. The organic matter is autochthonous in the coals and allochthonous in associated sandstones and siltstones. It consists of about 70% vitrinite, 20% inertinite, and 10% liptinite. The overall maceral group composition is the same for coals and dispersed organic matter. This surprising similarity is caused by a nearly exclusive input of land-plant derived organic matter to swamps and fluvial systems and a similar degree of preservation. Highest average liptinite contents (% of total macerals) were found in unrooted mudstones, highest average inertinite contents in coarse-grained siltstones and highest average vitrinite percentages in sandstones.Maturities of the sediments studied are well within the hydrocarbon generation window, e. g. vitrinite reflectivities range from 0.6% to 1.6%. Reflectivities measured on dispersed particles in clastic rocks are similar to those measured in coal seams. Calculations of the amount of methane generated indicate that coal seams contributed more to the total hydrocarbon generation than dispersed organic matter.
Zusammenfassung Das Oberkarbon des Ruhrgebietes besteht aus ca. 4000 Metern wechsellagernder Sandsteine, Siltsteine und Kohleflöze. Der Ablagerungsraum der Sedimente war eine Region mit tropischem Klima, genauer ein paralisches Environment mit unregelmäßig alternierenden Folgen von fluviatilen Sedimenten, marinen Transgressionen und verbreiteten Sumpfablagerungen. Der Anteil organischer Substanzen an der gesamten Sedimentmenge beträgt durchschnittlich 6%. 70% dieser organischen Masse ist in Kohleflözen angereichert, der Rest liegt verteilt in den klastischen Gesteinen vor. Die Herkunft der organischen Substanz in den Kohleflözen ist autochthon, die in den benachbarten Sand- und Siltsteinen allochton. Die Zusammensetzung des organischen Materials ist 70% Vitrinit, 20% Inertinit und 10% Liptinit. Die allgemeine Zusammensetzung nach Mazeral-Gruppen ist für die Kohleflöze und das verteilte Material in den Nachbargesteinen identisch. Diese Ähnlichkeit beruht auf der gemeinsamen Herkunft der organischen Substanz in Sümpfen und Flußsystemen, die fast ausschließlich von Landpflanzen bestimmt wird, und einer sich entsprechenden Konservierung.Der Reifegrad der analysierten Sedimente liegt innerhalb des Kohlenwasserstoff-Bildungsbereiches (die Vitrinit-Reflexionen reichen von 0,6–1,6%). Dabei entsprechen die in den klastischen Gesteinen beobachteten Reflexionswerte weitgehend denen der Kohleflöze. Anhand der Menge des erzeugten Methans läßt sich erkennen, daß der Anteil der Kohleflöze an der Kohlenwasserstoff-Produktion höher ist als der Anteil, den disperse organische Substanzen der Klastika beisteuern.
Résumé Dans la région minière de la Ruhr, le Carbonifère supérieur constitue une succession, épaisse de 4.000 m environ, de grès, de siltites et de charbon. Leur dépôt, dans un milieu paralique tropical, a été marqué par des alternances de sédimentation fluiviale, de transgressions marines occasionnelles, et d'épisodes marécageux; il en résulte une disposition cyclique irrégulière. La série sédimentaire contient dans l'ensemble 6% de matière organique en moyenne. Environ 70% de cette matière organique se trouve dans les couches de charbon où elle est autochtone; le reste est allochtone et dispersé dans les grès et siltites. La matière organique se répartit approximativement en 70% de vitrinite, 20% d'inertinite et 10% de liptinite. La composition moyenne du groupe «macéral» est la même pour les charbons et la matière organique dispersée. Cette identité surprenante est l'expression d'une alimentation provenant exclusivement de plantes terrestres et d'un même degré de conservation.La maturité des sédiments étudiés se situe à l'intérieur du domaine de genèse des hydrocarbures: le pouvoir réflecteur de la vitrinite s'échelonne entre 0,6% et 1,6%. Les gradients du pouvoir réflecteur observés dans les roches détritiques et dans les couches de charbon sont analogues. Le calcul de la quantité de méthane engendré indique que la contribution des couches de charbon à la production totale d'hydrocarbure est supérieur à celle de la matière organique dispersée.
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![ycy](/content/j6857h50024429p7/xxlarge1099.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![zhcy](/content/j6857h50024429p7/xxlarge1078.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) . ![Dcy](/content/j6857h50024429p7/xxlarge1044.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![ecy](/content/j6857h50024429p7/xxlarge1101.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![dcy](/content/j6857h50024429p7/xxlarge1076.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![mcy](/content/j6857h50024429p7/xxlarge1084.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![yacy](/content/j6857h50024429p7/xxlarge1103.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![mcy](/content/j6857h50024429p7/xxlarge1084.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) 6%.70 % ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![tscy](/content/j6857h50024429p7/xxlarge1094.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ucy](/content/j6857h50024429p7/xxlarge1091.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![softcy](/content/j6857h50024429p7/xxlarge1100.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ycy](/content/j6857h50024429p7/xxlarge1099.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) , ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![ycy](/content/j6857h50024429p7/xxlarge1099.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![dcy](/content/j6857h50024429p7/xxlarge1076.gif) . ![Ocy](/content/j6857h50024429p7/xxlarge1054.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![ucy](/content/j6857h50024429p7/xxlarge1091.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![softcy](/content/j6857h50024429p7/xxlarge1100.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ycy](/content/j6857h50024429p7/xxlarge1099.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![yacy](/content/j6857h50024429p7/xxlarge1103.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![yacy](/content/j6857h50024429p7/xxlarge1103.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![khcy](/content/j6857h50024429p7/xxlarge1093.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) , ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![yucy](/content/j6857h50024429p7/xxlarge1102.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) — ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![khcy](/content/j6857h50024429p7/xxlarge1093.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![softcy](/content/j6857h50024429p7/xxlarge1100.gif) . ![Ocy](/content/j6857h50024429p7/xxlarge1054.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![mcy](/content/j6857h50024429p7/xxlarge1084.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) 70 % ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) , ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) 20% ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) 10% ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) . ![Scy](/content/j6857h50024429p7/xxlarge1057.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![mcy](/content/j6857h50024429p7/xxlarge1084.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![tscy](/content/j6857h50024429p7/xxlarge1094.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ucy](/content/j6857h50024429p7/xxlarge1091.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![softcy](/content/j6857h50024429p7/xxlarge1100.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![dcy](/content/j6857h50024429p7/xxlarge1076.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![yucy](/content/j6857h50024429p7/xxlarge1102.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![dcy](/content/j6857h50024429p7/xxlarge1076.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) . ![Ecy](/content/j6857h50024429p7/xxlarge1069.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![bcy](/content/j6857h50024429p7/xxlarge1073.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![bcy](/content/j6857h50024429p7/xxlarge1073.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![khcy](/content/j6857h50024429p7/xxlarge1093.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![zhcy](/content/j6857h50024429p7/xxlarge1078.gif) ![dcy](/content/j6857h50024429p7/xxlarge1076.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) 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![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ; ![ecy](/content/j6857h50024429p7/xxlarge1101.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![chcy](/content/j6857h50024429p7/xxlarge1095.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![shchcy](/content/j6857h50024429p7/xxlarge1097.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) 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![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ucy](/content/j6857h50024429p7/xxlarge1091.gif) ![kcy](/content/j6857h50024429p7/xxlarge1082.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![tscy](/content/j6857h50024429p7/xxlarge1094.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![zcy](/content/j6857h50024429p7/xxlarge1079.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![khcy](/content/j6857h50024429p7/xxlarge1093.gif) ![rcy](/content/j6857h50024429p7/xxlarge1088.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) . ![Scy](/content/j6857h50024429p7/xxlarge1057.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![iecy](/content/j6857h50024429p7/xxlarge1077.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) 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![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![softcy](/content/j6857h50024429p7/xxlarge1100.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![gcy](/content/j6857h50024429p7/xxlarge1075.gif) ![pcy](/content/j6857h50024429p7/xxlarge1087.gif) ![lcy](/content/j6857h50024429p7/xxlarge1083.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![tcy](/content/j6857h50024429p7/xxlarge1090.gif) . ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![scy](/content/j6857h50024429p7/xxlarge1089.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![ocy](/content/j6857h50024429p7/xxlarge1086.gif) ![vcy](/content/j6857h50024429p7/xxlarge1074.gif) ![acy](/content/j6857h50024429p7/xxlarge1072.gif) ![ncy](/content/j6857h50024429p7/xxlarge1085.gif) ![icy](/content/j6857h50024429p7/xxlarge1080.gif) 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![lcy](/content/j6857h50024429p7/xxlarge1083.gif) .
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