A strategy for the use of bomb-produced radiocarbon as a tracer for the transport of fossil fuel CO2 into the deep-sea source regions

Because the equilibration time for CO₂ gas between the surface ocean and atmosphere is an order of magnitude shorter than the equilibration time for the isotopes of carbon, bomb-produced radiocarbon cannot be simply used as a tracer for fossil fuel CO₂. This difference is especially important for the areas of deep water formation. In this paper we derive the relationship between the isotopic equilibration time and chemical equilibration times for carbon between sea and air. We also show that if the distribution of a second transient tracer is measured, it is possible to circumvent the ambiguity associated with this exchange time difference. Tritium, while adequate in purely diffusive models, is not ideal as the second transient in models involving advection (i.e., downwelling). For such models⁸⁵Kr or freon is a much better choice.