Experimental constraints on ultrapotassic magmatism from the Bohemian Massif (durbachite series, Czech Republic) |
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Authors: | Fleurice Parat François Holtz Milo? René Renat Almeev |
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Institution: | 1. Institut für Geowissenschaften, Mineralogie-Geochemie, Universit?t Freiburg, Albertstra?e 23b, 79104, Freiburg, Germany 2. Institut für Mineralogie, Leibniz Universit?t Hannover, Callinstrasse 3, 30167, Hannover, Germany 3. Institute of Rock Structure and Mechanics, ASCR V, Hole?ovi?kách 41, 182 09, Prague, Czech Republic
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Abstract: | The equilibrium phase relations of a mafic durbachite (53 wt.% SiO2) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have
been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H2O activity (1.1–6.1 wt.% H2O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO
buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for
the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite
and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to
low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H2O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus
assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar
to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally
and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence
olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation
trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes
and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing
metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation
of a more mafic parent and mixing with mantle-derived components at mid crustal pressures. |
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