Recent changes in heavy metal storage in flood-plain soils of the Lahn River,central Germany

Between 1995 and 2007, the concentrations of Pb and Zn in floodplain soils increased along a 60-km reach of the Lahn River, Germany, suggesting that the storage of some metals in the fluvial system is out of phase with recent declines in the release of metals to the environment. Re-sampling of surface soils to 5 cm along five transects perpendicular to the river indicated that the concentration of Pb increased between 1995 and 2007 along two transects and was statistically unchanged at the other three. The concentration of Zn increased at three of five transects and was statistically unchanged at two transects over the same time period. Between 1995 and 2007, concentrations of Cu were statistically equal along four of five transects and declined at the other transect. The increase in Pb and Zn was greater in a more rural than in a more urbanized reach of the Lahn River. Soil texture and organic matter content had virtually no impact on the concentration of metals. The increase in Pb concentration suggests a lag between the decline in Pb releases to the environment and its movement through the fluvial system. Increased Zn storage may result from the high solubility of the metal and the relative ease with which it moves through the environment. Environmental controls appear to have slowed Cu storage along the Lahn River, but are not yet reflected in Pb and Zn storage.