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Measurement of the photodissociation coefficient of NO2 in the atmosphere: II,stratospheric measurements
Authors:S. Madronich  D. R. Hastie  H. I. Schiff  B. A. Ridley
Affiliation:(1) Department of Chemistry, York University, M3J 1P3 Downsview, Ontario, Canada;(2) Present address: National Center for Atmospheric Research, PO Box 3000, 80307 Boulder, CO, U.S.A.
Abstract:The photodissociation coefficient of NO2, JNO2, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported. High Sun values of JNO2 measured were 10.5±0.3 and 10.3±0.3×10-3 s-1 at 24 and 32 km respectively. The decrease in JNO2 at sunset was monitored in both flights. The measurements are found to be in good agreement with calculations of JNO2 using a simplified isotropic multiple scattering computer routine.
Keywords:JNO2  NO2 photolysis  atmospheric photochemistry  JNO2 measurement
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