Measurement of the photodissociation coefficient of NO2 in the atmosphere: II,stratospheric measurements |
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Authors: | S. Madronich D. R. Hastie H. I. Schiff B. A. Ridley |
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Affiliation: | (1) Department of Chemistry, York University, M3J 1P3 Downsview, Ontario, Canada;(2) Present address: National Center for Atmospheric Research, PO Box 3000, 80307 Boulder, CO, U.S.A. |
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Abstract: | The photodissociation coefficient of NO2, JNO2, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported. High Sun values of JNO2 measured were 10.5±0.3 and 10.3±0.3×10-3 s-1 at 24 and 32 km respectively. The decrease in JNO2 at sunset was monitored in both flights. The measurements are found to be in good agreement with calculations of JNO2 using a simplified isotropic multiple scattering computer routine. |
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Keywords: | JNO2 NO2 photolysis atmospheric photochemistry JNO2 measurement |
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