Study of metal sorption/desorption processes on competing sediment components with a multichamber device |
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Authors: | Wolfgang Calmano Wolfgang Ahlf Ulrich Förstner |
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Institution: | (1) University of Technology Hamburg-Harburg, Eissendorferstrasse 38, D-2100 Hamburg 90, West Germany |
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Abstract: | A new multichamber device was developed to study sorption/desorption reactions of metals on different competing sediment components
and the influence of environmental factors on these reactions. The system consists of a central chamber connected with six
external chambers and separated by 0.45-μm-diameter membranes.
The diffusion kinetics of metals between the single chambers were determined. Equilibrium was attained within 24 h. Algal
cell walls (Scenedesmus quadricauda), bentonite, aluminium oxide, managese oxide, quartz powder, and goethite were used as model sediment components. Determination
of metal sorption on the solid phases resulted in a significant enrichment on the algal cell walls, particularly for Cu and
Cd. It was concluded that sorption depends not only on ion exchange but also on complexing reactions which lead to relatively
stable surface binding. A second series of experiments investigated the effect of seawater on sediment components and dredged
mud. Cadmium was remobilized from all solid components, but Cu was not remobilized from algal cell walls and bentonite.
The dominant role of organic substrates in the binding of metals such as Cd andCu is of particular relevance for the transfer
of these elements into biological systems. Even relatively small percentages of organic substrates, if involved in metabolic
processes, may constitute a major pathway by which metals are transferred within the food chain. |
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