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Iron Isotopic Compositions of Geological Reference Materials and Chondrites
Authors:Paul R Craddock  Nicolas Dauphas
Institution:Origins Laboratory, Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637, USA
Abstract:High‐precision iron isotopic compositions for Fe‐bearing geological reference materials and chondrites with a wide range of matrices (e.g., silicates, oxides, organic‐bearing materials) are reported. This comprehensive data set should serve as a reference for iron isotopic studies across a range of geological and biological disciplines for both quality assurance and inter‐laboratory calibration. Where comparison is available, the iron isotopic compositions of most geological reference materials measured in this study were in agreement with previously published data within quoted uncertainties. Recommendations for the reporting of future iron isotopic data and associated uncertainties are also presented. Long‐term repeat analyses of all samples indicate that highly reproducible iron isotopic measurements are now obtainable (± 0.03‰ and ± 0.05‰ for δ56Fe and δ57Fe, respectively).
Keywords:mass spectrometry  certified reference materials  geological reference materials  iron  isotope ratios  precise determination  calibration  spectrometrie de mass  maté  riaux de ré    rence certifié  es  maté  riaux de ré    rence gé  ologiques  fer  rapports isotopiques  determinations pré  cises  calibration
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