| 胶州湾海水中一氧化碳光致生成影响因素的研究 |
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| 引用本文： | 陆小兰,张聪,杨桂朋,谭勇,任春艳. 胶州湾海水中一氧化碳光致生成影响因素的研究[J]. 海洋学报(英文版), 2012, 31(4): 77-83 |
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| 作者姓名： | 陆小兰 张聪 杨桂朋 谭勇 任春艳 |
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| 作者单位： | 中国海洋大学 海洋化学理论与工程技术教育部重点实验室, 山东 青岛 266100;中国海洋大学 海洋化学理论与工程技术教育部重点实验室, 山东 青岛 266100;中国海洋大学 海洋化学理论与工程技术教育部重点实验室, 山东 青岛 266100;中国海洋大学 海洋化学理论与工程技术教育部重点实验室, 山东 青岛 266100;青岛农业大学 化学与药学院, 山东 青岛 266109 |
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| 基金项目： | 国家自然科学基金项目(40606023,40976043);国家杰出青年科学基金(40525017);教育部"长江学者"奖励计划;山东省"泰山学者"建设工程专项经费资助。 |
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| 摘 要： | 海水中的一氧化碳(CO)主要由溶解有色有机物(CDOM)光降解产生,且CO的光致生成量受到环境因素的影响。采集了胶州湾及其河口表层水样,通过实验室模拟实验开展了不同的环境条件(辐射强度、光照时间、温度、pH和盐度)以及水体中CDOM的来源对CO光致生成的影响研究。结果表明胶州湾海水中CO的光致生成速率随辐射强度的增强、水温的升高和水体pH的增大而增大;随着光照时间的延长、水体盐度的增大而逐渐减小;不同来源的CDOM对水体中CO的光致生成速率产生了不同的影响。
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| 关 键 词： | 一氧化碳 光致生成 溶解有色物质 |
| 收稿时间： | 2011-05-09 |
| 修稿时间： | 2012-02-09 |
Studies of influencing factors on photoproduction of carbon monoxide in sea water of the Jiaozhou Bay |
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| LU Xiaolan,ZHANG Cong,YANG Guipeng,TAN Yong and REN Chunyan. Studies of influencing factors on photoproduction of carbon monoxide in sea water of the Jiaozhou Bay[J]. Acta Oceanologica Sinica, 2012, 31(4): 77-83 |
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| Authors: | LU Xiaolan ZHANG Cong YANG Guipeng TAN Yong REN Chunyan |
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| Affiliation: | Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;College of Chemistry & Pharmacy, Qingdao Agricultural University, Qingdao 266109, China |
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| Abstract: | In the ocean,CO is mainly photoproduced by chromopheric dissolved organic matter (CDOM).It is of vital significance to study the effects of environmental factors,including radiation intensity,irradiation time,water temperature,pH,salinity and photobleaching time of CDOM,on CO photoproduction in seawater.The above mentioned variables on CO photoproduction were examined in surface seawater in the Jiaozhou Bay and its several river mouths in this paper.The results indicate that photoproduction rates of CO increase with radiation intensity,irradiation time,water temperature,pH and decrease with wavelength,salinity,respectively.Photoproduction rates of CO are different due to CDOM of various sources in the photochemical reactions. |
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| Keywords: | carbon monoxide photoproduction rate CDOM |
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