Fayalitic olivine in matrix of the Krymka LL3.1 chondrite: Vapor-solid growth in the solar nebula

Abstract— Fayalitic olivine (Fa_54–94) is a ubiquitous component in the matrix of Krymka (LL3.1) as well as in other highly unequilibrated chondrites (ordinary and carbonaceous). In Krymka, the fayalitic olivine has an unusual anisotropic platy morphology that occurs in at least five types of textural settings that can be characterized as: (1) isolated platelets, (2) clusters of platelets, (3) euhedral to subhedral crystals, (4) overgrowths of platelets on forsteritic olivine, and (5) fluffy (porous) aggregates. From transmission electron microscope (TEM) investigation, the direction of elongation of the platy olivine overgrowths on forsteritic olivine substrates is along the c axis and in most cases it corresponds with the c axis of the substrate olivine, which suggests that the fayalitic olivine grew in this unusual morphology and is not a replacement product of preexisting material. The fayalitic olivine in the matrix of Krymka is compositionally similar to olivine with platy morphology in the matrix of some CV3 chondrites and both have similar Fe/Mn ratios, but important morphological differences indicate that their relationship needs to be explored further. Textural and compositional data indicate that the fayalitic olivine in the matrix of Krymka, as well as in some other unequilibrated ordinary chondrites, formed prior to final lithification of the meteorite and probably prior to parent body accretion. We find that formation of the fayalitic olivine by vapor-solid growth provides the best explanation for our observations and data and is the only feasible mechanism for the formation of fayalitic olivine in the matrix of Krymka. We propose that the fayalitic olivine formed by vaporization and recondensation of olivine rich-dust, during a period of enhanced dust/gas ratio in the nebula.