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| 原油裂解成气动力学参数及其应用研究 | |
| 引用本文： | 李贤庆,仰云峰,田辉,肖贤明,黄孝波,王萌,杨朝世. 原油裂解成气动力学参数及其应用研究[J]. 沉积学报, 2012, 30(6): 1156-1164 |
| 作者姓名： | 李贤庆 仰云峰 田辉 肖贤明 黄孝波 王萌 杨朝世 |
| 作者单位： | 1. 中国矿业大学煤炭资源与安全开采国家重点实验室,北京100083／中国矿业大学地球科学与测绘工程学院,北京100083 2. 中国石油化工股份有限公司石油勘探开发研究院无锡石油地质研究所,江苏无锡,214151 3. 中国科学院广州地球化学研究所有机地球化学国家重点实验室,广州,510640 4. 中国石油塔里木油田分公司勘探开发研究院,新疆库尔勒,841000 |
| 基金项目： | 中央高校基本科研业务费专项，国家科技重大专项，有机地球化学国家重点实验室开放基金，煤炭资源与安全开采国家重点实验室自主科研课题( |
| 摘 要： | 采用黄金管限定体系，对塔里木盆地牙哈、哈得原油样品进行了热模拟实验，研究了原油样品热裂解生成气态烃的产率特征及其动力学参数。结果表明，牙哈、哈得原油样品裂解具有高的C1-5产率(738.87 ml/g、598.98 ml/g)和C2-5产率(256.85 ml/g、188.63 ml/g)。牙哈、哈得原油样品裂解成气动力学参数存在差异:牙哈原油样品裂解气甲烷、乙烷、丙烷生成的活化能范围分别为（66～83）×4.186 kJ/mol、（59～72）×4.186 kJ/mol、（59～65）×4.186 kJ/mol，频率因子各为2.07×1016s-1、1.0×1014s-1、1.0×1014s-1；哈得原油样品裂解气甲烷、乙烷、丙烷生成的活化能范围分别为(63～84)×4.186 kJ/mol、(57～63)× 4.186 kJ/mol、(58～70)×4.186 kJ/mol，频率因子各为1.42×1016s-1、1.0×1014s-1、1.0×1014s-1。以塔东地区满东1气藏为例进行了动力学模拟应用研究，认为原油的大量裂解为满东1气藏提供了主要气源。 |
| 关 键 词： | 原油裂解 气态烃产率 动力学参数 热模拟实验 塔里木盆地 |
Study on Kinetic Parameters of Crude Oil Cracking Gas and Its Application |
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| LI Xian-qing,YANG Yun-feng,TIAN Hui,XIAO Xian-ming,HUANG Xiao-bo,WANG Meng,YANG Chao-shi. Study on Kinetic Parameters of Crude Oil Cracking Gas and Its Application[J]. Acta Sedimentologica Sinica, 2012, 30(6): 1156-1164 | |
| Authors: | LI Xian-qing YANG Yun-feng TIAN Hui XIAO Xian-ming HUANG Xiao-bo WANG Meng YANG Chao-shi |
| Affiliation: | 1.State Key Laboratory of Coal Resources and Safe Mining,China University of Mining and Technology,Beijing 100083; 2.College of Geoscience and Surveying Engineering,China University of Mining and Technology,Beijing 100083; 3.Wuxi Institute of Petroleum Geology,Petroleum Exploration and Production Research Institute,Sinopec,Wuxi,Jiangsu 214151; 4.State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640; 5.Research Institute of Exploration and Development,Tarim Oilfield Company,PetroChina,Korla,Xinjiang 841000) |
| Abstract: | The thermal simulation experiment of Yaha and Hade crude oil samples in Tarim Basin was carried out, by using the gold tube confined system. The yield characteristics and kinetic parameters of cracking gases from Yaha and Hade oil samples were studied. The results demonstrate that the Yaha and Hade oil samples have high total gas yields (738.87 ml/g, 598.98 ml/g) and C2 5 yields (256.85 ml/g, 188.63 ml/g). Differences are existed in the kinetic parameters of cracking gases in the Yaha and Hade oils. The activation energy distributions of methane, ethane and propane generated from the Yaha oil sample are in the range of (66～83)×4.186kJ/mol, (59～72)×4.186kJ/mol, and (59～65)×4.186kJ/mol. Their frequency factors from the Yaha oil sample are 2.07×1016s-1, 1.0×1014 s-1, and 1.0×1014s-1, respectively. The activation energy distributions of methane, ethane and propane from the Hade oil sample are in the range of (63～84)×4.186 kJ/mol, (57～63)×4.186 kJ/mol, and (58～70)× 4.186 kJ/mol. Their frequency factors from the Hade oil sample are 1.42×1016s-1, 1.0×1014s-1, and 1.0×1014s-1, respectively. The Mandong 1 gas pool in the eastern Tarim Basin was taken as an example and its kinetic modeling of gas generation was studied. It is suggested that gas source of the Mandong 1 gas pool was resulted from a large number of crude oil cracking. |
| Keywords: | crude oil cracking gaseous hydrocarbon yield kinetic parameter thermal simulation experiment TarimBasin |
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