Physical and chemical response of zircons to deformation

An investigation of U-Pb isotopic systematics in zircons from mylonitized Henderson Gneiss (Sinha and Glover 1978) revealed that selected zircon fractions from the mylonite zone suffered total loss of radiogenic Pb at 460 m.y. To further investigate the relationship between Pb loss, U gain, and grain size reduction associated with increasing strain in the shear zone, we have characterized the chemistry and morphology of zircons in the mylonitic rocks, using both electron microprobe analysis and scanning electron microscopy.SEM photographs of the zircons indicate that strain-correlated fracturing and size reduction of the zircons accompanied Pb loss throughout the mylonite zone. Stresses imposed by the expansion of initially U-rich, -damaged portions of the crystal resulted in microfracturing of the more brittle crystalline material proximal to the U-rich zones. During mylonitization, fractures propagated preferentially along these zones allowing metamorphic fluids to penetrate the easily-leached, -damaged portions of the zircons. Removal of 75% of the radiogenic Pb from zircons in the least-deformed zone of the mylonites may have occurred via this mechanism.Irregular, porous zircon overgrowths are also evident from the SEM photographs. Overgrowths are strongly enriched in U, Y and P with respect to the relict, Henderson Gneiss-derived cores, and tend to increase in volume from the protomylonite to the blastomylonite. Thus, the development of overgrowths on the zircons accounts for the U gain observed by Sinha and Glover (1978), and indicates that the transport of high field strength cations (e.g., Zr⁴⁺, Hf⁴⁺, U⁴⁺, etc.) occurred during prograde mylonitization at 460 m.y.A retrograde shearing event at 273 m.y. caused no further disturbance in the U-Pb isotopic systematics of the zircons. Pb retention by zircons during the later episode may have been the result of 1) the participation of H₂O-rich, relatively noncorrosive fluids and/or 2) the lack of further fracturing and size reduction in a strain gradient of lower magnitude than the prograde event.