Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May–June, 2004 |
| |
| Authors: | Z-H Shon G Lee S-K Song M Lee J Han D Lee |
| |
| Institution: | (1) Department of Environmental Engineering, Dong-Eui University, 995 Eomgwangno, Busanjin-Gu, Busan, 614-714, South Korea;(2) Department of Environmental Sciences, Hankuk University of Foreign Studies, San 89, Wangsanri, Chuin-Gu, Yongin, 449-791, South Korea;(3) Department of Atmospheric Sciences, Pusan National University, San 30, Jangjeun-dong, Geumjeong-Gu, Busan, 609-735, South Korea;(4) Department of Earth and Environmental Sciences, Korea University, Anam-dong, Seongbuk-Gu, Seoul, 136-701, South Korea;(5) Division of Atmospheric Environment, National Institute of Environmental Research, Environmental Research Complex, Kyungseo-dong, Seo-Gu, Inchon, 404-170, South Korea;(6) Department of Chemistry, Yonsei University, 134 Sinchon, Seodaemun-Gu, Seoul, 120-749, South Korea |
| |
| Abstract: | This study examines the general characteristics of reactive nitrogen oxides (NOy) at urban and rural sites in terms of measurement- and modeling-based analyses. In this field study, NOx at urban and rural sites were 92 and 89% of NOy on average, respectively. HONO levels (e.g., 1.8 ppbv) at the urban site were significantly higher than those at the rural
site by a factor of 4.5. HONO concentrations at the urban site during the night were clearly higher than those during the
day, which were likely to result from heterogeneous reactions on the surfaces of airborne aerosols and/or grounds. In contrast,
there were no significant differences of PAN concentrations in either the temporal or spatial distributions. The significantly
low ratios of NOz/NOy at both sampling sites indicated a more limited chemical aging process in air mass. O3 levels were weakly related to NOx oxidation at both sites, especially at the rural site. |
| |
| Keywords: | Urban Rural Nitrogen oxides HONO Modeling based analysis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
