Infrared and Raman spectra of lunar samples from Apollo 11, 12 and 14

We report the room temperature infrared reflectance spectra of several lunar surface rocks in the form of polished slices or butt ends. The spectra were obtained over the frequency range 20-2000 cm^–1 throughout the mid and far infrared (5-500µ) region of the electromagnetic spectrum where the fundamental internal and lattice vibrational modes of all minerals and rocks occur.Some fines samples were examined as pressed pellets and their reflectivities compared with the bulk samples. Several terrestrial minerals and rocks were also investigated. Kramers-Kronig analyses of these reflectance spectra were undertaken and the dispersion of the dielectric response ( and ) and the optical constants (n andk) have been determined over this frequency range. The low frequency and high frequency (infrared) dielectric constants were also calculated from the reflectance data.Raman light scattering measurements were made on all the samples supplied from the first three Apollo missions. Large background scattering proved to be the greatest experimental problem. Successful spectra in nearly all cases were obtained from small crystalline inclusions imbedded in the main ground mass. Some crystalline bulk rocks containing many very fine inclusions gave identifiable spectra and at least three different types were obtained.Supported by NASA Grant NGR 22-011-069 and by a Northeastern University Grant for Basic Research.