The late- to postorogenic transition in the Apiaí domain,SE Brazil: Constraints from the petrogenesis of the Neoproterozoic Agudos Grandes Granite Batholith

A remarkable change in the typology of granite magmatism occurred during the late evolution of the Agudos Grandes Batholith (Apiaí domain, SE Brazil), marked by the appearance of A-type granites some 10–15 Myr after the last manifestations of the compressional period. The elemental and Sr–Nd isotope geochemistry of the approximately 600 Ma, “late-orogenic”, moderately peraluminous Piedade, Serra dos Lopes, and Pilar do Sul granites shows that the middle crust was heated to approximately 820–850 °C during the latest stages of the compressional period and generated large amounts of melt through biotite dehydration–melting of gneiss protoliths. These crustal magmas either formed independent intrusions or mixed in varied proportions with raising high-K calc-alkaline magmas, as suggested by continuous trends toward more mafic granites (65–70 wt% SiO₂), which have the geochemical signature of contaminated calc-alkaline magmas. The postorogenic granites occur as two subgroups with different age (～585 and ～565 Ma), both with the chemical fingerprints typical of A-type granites (low mg#, Ba, and Sr; high Zr, Hf, Nb, and Y), interpreted as a result of crustal melting at lower P, fO₂, and a(H₂O) and higher T (up to 870 °C, indicated by zircon saturation). Significant trace-element and radiogenic isotope contrasts (e.g., εNd_T = ?16 vs. ?11) show that the two postorogenic subgroups derived from different sources. A Sr–Nd isotope signature nearly identical to the “end-member” late-orogenic crustal melts suggests that the older postorogenic granites derived from a similar (but probably less fertile) source. The less negative εNd_T of the young subgroup is unmatched by known crustal sources in the Apiaí domain and may have resulted from either an infracrustal component or mobilization of an unexposed section with less crustal residence time.