Abstract: | The effects of magma fragmentation and atmospheric transport of pyroclasts in modifying tephra chemistry are quantitatively examined in order to assist in devising geochemical sampling strategies for young pyroclastic deposits, with particular regard to air-fall tephra. Magma fragmentation during explosive eruption results in crystal fractionation, the extent of which increases with decreasing tephra particle size. Among the products of a single sustained plinian eruption, variable atmospheric flight times of pyroclasts may cause simultaneous deposition of earlier-erupted and later-erupted material. Both of these processes will affect the degree and nature of chemical variations found in individual pyroclastic deposits. Their effects may be largely overcome by sampling coarse tephra within a narrow grain-size range. |