Estimation of LNAPL saturation in fine sand using time-domain reflectometry / Estimation de la saturation en LPNAL dans du sable fin grâce à la réflectométrie en domaine temporel

Abstract

Abstract Recently, substantial progress has been made in detection and observation of non-aqueous phase liquids (NAPLs) in the subsurface using different experimental techniques. However, there is still a lack of appropriate direct methods to measure the saturation of NAPL (θ_NAPL). This paper provides a guide for estimating θ_NAPL and water content (θ _w ) in unsaturated and saturated sand based on direct measurements of soil dielectric constant (K_a ) and electrical conductivity (σ _a ) using time domain reflectometry (TDR). The results show that the previously used dielectric mixing model fails to predict θ_NAPL in the case of a four-phase system. A new methodology is suggested and exemplified by showing that the measured K_a gives accurate estimation of θ_NAPL for a three-phase system while in a four-phase system, both θ _a and K_a need to be measured. The results show that using the suggested methodology, accurate predictions of θ _w (R ² = 0.9998) and θ_NAPL lower than 0.20 m³ m^-3 (average R ² = 0.9756) are possible.