Petrogenesis of the Kinsman Intrusive Suite: Peraluminous Granitoids of Western New Hampshire

The Kinsman Intrusive Suite occurs in six major plutons of westernNew Hampshire, covering a total area of 2240 km². It is an Acadian-agesyntectonic gneissic S-type peraluminous granitoid, rangingin composition from quartz diorite to granite. Much of the Kinsmanis characterized by very large (up to 120 mm in maximum dimension)megacrysts of alkali feldspar, but the bulk chemistry of therocks indicates that these cannot be phenocrysts crystallizedfrom initially homogeneous melts. Locally, there is abundant(20 per cent) almandine-rich garnet, and graphite is a commonaccessory.In contrast to the unannealed orthoclase in surroundingmetapelites, the alkali feldspar of the Kinsman has, for themost part, inverted to maximum microcline. The garnets havecore temperatures in the range of 800 to 900 ?C, and are pseudomorphedby, or show reaction rims to, biotite. Plagioclase commonlyshows zoning, some of it oscillatory. These features are magmaticin nature, and argue against the conclusions of previous investigatorsthat the mineralogy and textures of the rock are due to regionalmetamorphism of a previously-crystallized two-mica granitoidwhich has undergone prograde reactions such as:muse + bio +3 qtz 2 Kfs + gar + 2H₂O.The intrusives have also producedrecognizable contact-metamorphic features in the wallrocks andare probably coeval with the dominant M2 Acadian metamorphism.Majorelement analytical data for the Kinsman suite has been examinedby least squares mixing-model and extended Q-mode factor analysis.These calculations, supported by consideration of REE data,suggest that the most likely origin for the Kinsman magmas isby deep-crustal anatexis of slightly calcareous metapelites,and involves a reaction such as:bio + Al₂SiO₅ + qtz + feldspars gar + cord + Kfs + plag + melt.In non-calcareous pelites thisreaction produces a water-undersaturated peraluminous melt attemperatures above 700 ?C, and allows for the early crystallizationor recrystallization of K-feldspar, plagioclase, and garnetin a crystal-liquid mush or migma. Geochemically, garnet + plagioclaseare treated as restite, and a minimum-melt granite as the magmain the Q-mode and mixing-model calculations. The variabilityin chemistry of the Kinsman Intrusive Suite is best explainedon the basis of mixing of leucogranitic anatectic melts withgarnet-plagioclase restitic material and a quartz-feldspar-sillimanite-biotiterock, but only very slightly affected by crystal settling.