Integrated investigation of the mixed origin of lunar sample 72161,11

Sample 72161,11 (dark mantle at LRV-3) has a graphic mean grain size (M _z) of 3.88 ø, inclusive graphic standard deviation (σ _I) of 1.29, and a total carbon content of 204µg C g^?1 sample, and is, therefore, quite mature. However, the agglutinate content is only 30% in the 90–177µm particles, indicating an apparent departure from steady state. Analyses of C, CH₄, and H₂ concentrations in size fractions larger than 149µm show that the volume correlated component of these species increases with increasing grain size. In a homogeneous agglutinate population the volume correlated component is expected to be independent of grain size. The observed increase can be interpreted in terms of the mixing of a dominant local population of coarser agglutinates, with high carbon and hydrogen, with an imported population of finer agglutinates relatively poor in carbon and hydrogen. When analyses of size-fractions from the bulk sample are considered, these effects are apparently obliterated by the admixture of coarse-grained material low in agglutinates. It seems likely that this low agglutinate content is a consequence of the breakdown of the fragile, large agglutinates in the imported material during their movement to the sample site.