Silicon isotopes in the inner Solar System: Implications for core formation, solar nebular processes and partial melting

We report Si isotopic data on a suite of terrestrial mantle-derived samples, meteorites and a lunar sample. Our data on co-existing mantle minerals, peridotites and basalts demonstrate lack of any resolvable high temperature fractionation during igneous processes. We show that the δ³⁰Si of the bulk silicate Earth (BSE) is identical, within analytical uncertainties, to carbonaceous and ordinary chondrites (CHUR). Based on our data the difference between δ³⁰Si_BSE and δ³⁰Si_CHUR is 0.035 ± 0.035. Whole-rock differentiated meteorites from different parent bodies (Mars, Vesta) and a lunar breccia sample also show similar δ³⁰Si suggesting broad-scale Si isotope homogeneity in the inner Solar System with an average δ²⁹Si = −0.20 ± 0.01 and δ³⁰Si = −0.39 ± 0.02 relative to the NBS28 Si isotope standard.A difference between δ³⁰Si_BSE and δ³⁰Si_CHUR of 0.035, as observed in our study, translates to less than 1.67 wt.% Si in the core considering a continuous accretion model whereas estimates using a batch model are even lower. Within uncertainties (±0.035‰) in the δ³⁰Si difference between the BSE and CHUR, a maximum of 3.84 wt.% Si could be present in the Earth’s core whereas at δ³⁰Si_BSE-δ³⁰Si_CHUR = 0, there is no requirement of Si in the Earth’s core. Such low Si in the core necessitates the presence of other light elements in the core to explain its density deficit. Our data also places constraints on the oxidation state of the Earth’s mantle during core segregation. The uncertainties in estimating the concentration of oxidized Fe in the mantle during the first 90% of accretion arise from uncertainties in the estimates of the equilibrium partition coefficient of silicon between metal and silicate at conditions relevant to core formation. For δ³⁰Si_BSE-δ³⁰Si_CHUR = 0.035 ± 0.035, the concentration of oxidized Fe in the mantle during the first 90% of accretion could be as low as ∼1%. However, at δ³⁰Si_BSE-δ³⁰Si_CHUR = 0, the Si isotope data do not require any change in the mantle concentration of oxidized Fe during accretion from the present day value of 6.26%.