Metal in CR chondrites

In section many low-FeO CR chondrules are surrounded by rings of metal; this metal-cladding seems to have formed during chondrule melting events as films of metal that wetted the surface. Electron microprobe studies show that in each ring the metal is very uniform in composition, consistent with efficient mixing during formation of the metal film. In contrast the mean Ni contents of 13 different rings vary by up to a factor of 2. There is no FeS associated with ring metal. Ring metal Co is positively correlated with Ni but the Co/Ni ratio seems to decrease with increasing Ni. We observed a weak negative correlation between ring metal Ni and the fayalite content of the host olivine. Coarse interior metal has higher Ni contents than that in the surrounding rings. At any specific chondrule location, smaller grains tend to have lower Ni contents than larger grains. These trends in Ni seem to reflect two processes: (1) The mean Ni content of metal (and easily reduced sulfides or oxides) in chondrule precursor materials seems to have decreased with the passage of time; on average, the metal in earlier-formed chondrules had higher Ni contents than the metal in later-formed chondrules. (2) Some oxidized Fe was reduced during chondrule formation leading to lower Ni contents in small grains compared to large grains; prior to reduction the Fe was in FeS or in FeO in accessible (fine-grained) sites. We suggest that the compositional evolution of nebular solids was responsible for the interchondrule variations whereas reduction of minor amounts of FeS or FeO was responsible for the size-related small variations in Ni content. We suggest that, during chondrule formation events, CR chondrules experienced relatively long thermal pulses that were responsible for the thorough loss of FeS and the common granoblastic texture observed in low-FeO chondrules. The preservation of the structures of internal rings shows, however, that even though high temperatures occurred in the secondary chondrule, temperatures in the centers of large (>20 μm) metal and silicate grains in the primary chondrule did not get high enough to cause appreciable melting.