Scavenging,cycling and removal fluxes of 210Po and 210Pb at the Bermuda time-series study site

Quantifying relative affinities of Po and Pb in different populations of marine particulate matter is of great importance in utilizing ²¹⁰Po as a tracer for carbon cycling. We collected and analyzed water samples for the concentrations of dissolved and total ²¹⁰Po and ²¹⁰Pb from the upper 600 m of the water column at Bermuda Time-series Study site (September 1999–September 2000) to investigate their seasonality of concentrations and their activity ratio (²¹⁰Po/²¹⁰Pb activity ratio, AR). Sinking particles collected in sediment traps at depths of 500 m, 1500 m, and 3200 m from the Oceanic Flux Program (OFP) time-series sediment traps were analyzed over a period of 12 months (May 1999–May 2000). The objective was to compare the deficiencies of ²¹⁰Po with respect to ²¹⁰Pb in the water column to that measured in the sediment traps and to assess the relative affinities of Po and Pb with different particle pools.Inventories of ²¹⁰Po in the upper 500 m water column varied by a factor of 2, indicating seasonal variations of particulate flux dominated the removal of ²¹⁰Po. The ²¹⁰Po/²¹⁰Pb ARs in the dissolved phase were generally less than the secular equilibrium value (1.0) in the upper 600 m, while were generally greater than 1.0 in the particulate phase, indicating higher removal rates of ²¹⁰Po relative to ²¹⁰Pb by particulate matter. The measured fluxes of ²¹⁰Po and ²¹⁰Pb in the 500 m, 1500 m, and 3200 m traps increased with depth, while the ²¹⁰Po/²¹⁰Pb ARs decreased with depth except from May–August 1999. From the measured fluxes of ²¹⁰Po and ²¹⁰Pb at these three traps and the concentrations of ²¹⁰Po and ²¹⁰Pb in the water column, this region appears to be a sink for ²¹⁰Pb which is likely brought-in by lateral advection.