Valence state of iron in a condensate from the Luna 16 regolith

This paper reports the results of an X-ray photoelectron spectroscopic study of the condensate phase of regolith sample L1639 returned by the Luna 16 mission. The reduced Si⁰, Si²⁺, Al⁰, Ti²⁺, and Ti³⁺ forms were detected in the sample. Iron occurs in all valence states, and Fe³⁺ species were detected for the first time in the condensate. Minor Fe³⁺ concentrations were observed in the upper layers of the sample containing the maximum amounts of condensate products. The fraction of ferric Fe is 22%, and the Fe⁰: Fe²⁺: Fe³⁺ proportion is 33: 45: 22. The appearance of ferric Fe in the lunar condensate is explained by the reaction of FeO disproportionation occurring either at the stage of the expansion and cooling of impact-related vapor or directly in the condensed phase on the surface of regolith particles. This interpretation is supported by the results of a model experiment on augite vaporization and condensation. The experiment simulating impact vaporization was carried out on a laser set-up at a temperature of ∼3000–4000 K and a pulse duration of ∼10⁻³ s in a He atmosphere (P = 1 atm). The results of analyses provided compelling evidence that the condensate produced after augite vaporization contains Fe in all oxidation states, and the proportions of different valence forms approach the stoichiometry of the disproportionation reaction.