A Quartz-bearing Orthopyroxene-rich Websterite Xenolith from the Pannonian Basin, Western Hungary: Evidence for Release of Quartz-saturated Melts from a Subducted Slab

An unusual quartz-bearing orthopyroxene-rich websterite xenolithhas been found in an alkali basaltic tuff at Szigliget, Bakony–BalatonHighland Volcanic Field (BBHVF), western Hungary. Ortho- andclinopyroxenes are enriched in light rare earth elements (LREE),middle REE and Ni, and depleted in Nb, Ta, Sr and Ti comparedwith ortho- and clinopyroxenes occurring in either peridotiteor lower crustal granulite xenoliths from the BBHVF. Both ortho-and clinopyroxenes in the xenolith contain primary and secondarysilicate melt inclusions, and needle-shaped or rounded quartzinclusions. The melt inclusions are rich in SiO₂ and alkalisand poor in MgO, FeO and CaO. They are strongly enriched inLREE and large ion lithophile elements, and display negativeNb, Ta and Sr anomalies, and slightly positive Pb anomalies.The xenolith is interpreted to represent a fragment of an orthopyroxene-richbody that crystallized in the upper mantle from a hybrid meltthat formed by interaction of mantle peridotite with a quartz-saturatedsilicate melt that was released from a subducted oceanic slab.Although the exact composition of the slab melt cannot be determined,model calculations on major and trace elements suggest involvementof a metasedimentary component. KEY WORDS: quartz; mantle; silicate melt inclusion; SiO₂-rich melt; subduction; Carpathian-Pannonian Region