Geology,fluid inclusion geochemistry,and 40Ar/39Ar geochronology of the Wulasigou Cu deposit,and their implications for ore genesis,Altay, Xinjiang,China

The Wulasigou Cu deposit occurs as veins controlled by a NW-trending structure in a Devonian volcano-sedimentary basin of the Altay orogenic belt, Xinjiang, China. Igneous and sedimentary rocks exposed in the area have undergone greenschist-facies metamorphism. The ore-forming process can be divided into early, middle, and late stages, represented by, respectively, pyrite-quartz, polymetallic sulfide-quartz, and carbonate–quartz veins, veinlets, and/or replacement bodies. The early veins were deformed and brecciated during a compressional or transpressional event. The middle-stage veinlets filled fractures in the early-stage vein and alteration assemblages, and are undeformed, suggesting a tensional shear setting. The late-stage veinlets are mainly open-space fissure fillings that cut veins and replacement bodies formed in the earlier stages.Four types of fluid inclusions (FIs), including aqueous (W-type), mixed carbonic-aqueous (M-type), purely carbonic (C-type) and daughter mineral-bearing (S-type), have been identified in copper-related quartz and calcite from the Wulasigou deposit. The early-stage quartz contains M- and W-type primary FIs that completely homogenized at temperatures of 322–412 °C with low salinities of 0.9–6.5 wt.% NaCl equiv. In contrast, the late-stage quartz or calcite contains only the W-type FIs with homogenization temperatures of 101–234 °C, and salinities of 0.9–2.9 wt.% NaCl equiv. This indicates that the metallogenic system evolved from CO₂-rich, metamorphic to CO₂-poor, through input of meteoric fluids. All four types of FIs can only be observed in the middle-stage minerals, where they show evidence of vein formation during an episode of fluid immiscibility. These FIs homogenized at temperatures ranging mainly from 230 to 347 °C, with salinities clustering 2.7–10.2 wt.% NaCl equiv for the W-, M- and C-types, and 34.7–38.2 wt.% NaCl equiv for the S-type, respectively. The metal precipitation resulted from a decrease in copper solubility during the fluid immiscibility episode. The estimated trapping pressures for the middle-stage fluids are 1.55–3.55 kbar, suggesting an alternating lithostatic-hydrostatic fluid-system, controlled by fault-valve activity at a depth of 13–15.5 km.Muscovite separates from the middle-stage polymetallic-quartz veinlets yield a well-defined ⁴⁰Ar/³⁹Ar isotopic plateau age of 219.41 ± 2.10 Ma, and an ³⁹Ar/³⁶Ar - ⁴⁰Ar/³⁶Ar isochron age of 219.73 ± 2.17 Ma. This age postdates the final Paleo-Asia Ocean closure (at ca. 250 Ma) by about 30 Ma, and indicates that the Cu mineralization at Wulasigou has occurred in the Triassic continental collision setting. Hence, the Wulasigou Cu deposit may be the first example of orogenic lode Cu deposits formed in accretionary orogeny or continental collision.