INTERPRETATION OF COPPER AND ZINC CONTAMINATION IN THE AQUATIC ENVIRONMENT OF PENINSULAR MALAYSIA WITH SPECIAL REFERENCE TO A POLLUTED RIVER, SEPANG RIVER

Three different aquatic ecosystems(an urban pond,Kelana Jaya Pond;a polluted river,Sepang River;and the intertidal and offshore areas of the west coast of Peninsular Malaysia)with different sets of ecological backgrounds and human activities were reviewed and assessed for the levels of Cu and Zn contamination with special reference to those found in polluted sediments collected from the Sepang River.The discussion on the contamination levels of Cu and Zn in the aquatic environment of Peninsular Malaysia was based on a comparison of the metal contamination of 4 kinds of aquatic environments.The comparison of 4 different areas was based on ① total concentrations of 2 metals;② the concentrations and percentages of the nonresistant(EFLE,acid-reducible and oxidisable-organic)and resistant geochemical fractions;and ③ correlation coefficients(R-values)based on data of 4 areas separately and a combination of 4 areas.The Sepang River recorded nonresistant fractions of 63.1% for Zn and 55.8% for Cu in addition to slightly lower metal concentrations when compared to those(60%-70%)reported before the shutting down of the piggery activities in that area.These nonresistant metal percentages(55%-63%)indicated that the metal concentrations were still dominated by anthropogenic sources since nonresistant fraction of metals were mostly contributed by anthropogenic sources.The positive results from the four different aquatic environments assessed here provided strong evidence to show that Malaysia's aquatic environment had received anthropogenic Cu and Zn.The present study also showed that the percentage of the nonresistant fraction and the R-values based on correlation analysis of Cu and Zn could be used as indicators of Cu and Zn pollution in the Malaysian aquatic ecosystem.Based on the present data,the correlation coefficients(R-values)are potential indicators of EFLE Cu and acid-reducible Cu of the sediments.The use of R-values as indicators of metal pollution is suggested and it is applicable to other heavy metal data although it should be improved in future studies.

INTERPRETATION OF COPPER AND ZINC CONTAMINATION IN THE AQUATIC ENVIRONMENT OF PENINSULAR MALAYSIA WITH SPECIAL REFERENCE TO A POLLUTED RIVER, SEPANG RIVER

Three different aquatic ecosystems(an urban pond,Kelana Jays Pond;a polluted river,Sepang River;and the intertidal and offshore areas of the west coast of Peninsular Malaysia)with different sets of ecological backgrounds and human activities were reviewed and assessed for the levels of Cu and Zn contamination with special reference to those found in polluted sediments collected from the Sepang River.The discussion on the contamination levels of Cu and Zn in the aquatic environment of Peninsular Malaysia was based on a comparison of the metal contamination of 4 kinds of aquatic environments.The comparison of 4 different areas was based on①total concentrations of 2 metals;②the concentrations and percentages of the nonresistant(EFLE,acid-reducible and oxidisable-organic)and resistant geochemical fractions;and③correlation coefficients(R-values)based on data of 4 areas separately and a combination of 4 areas.The Sepang River recorded nonresistant fractions of 63.1%for Zn and 55.8%for Cu in addition toslightly lower metal concentrations when compared to those(60%-70%)reported before the shutting down of the piggery activities in that area.These nonresistant metal percentages(55%-63%)indicated that the metal concentrations were still dominated by anthropogenic sources since nonresistant fraction of metals were mostly contributed by anthropogenic sources.The positive results from the four different aquatic environments assessed here provided strong evidence to show that Malaysia's aquatic environment had received anthropogenic Cu and Zn.The present study also showed that thepercentage of the nonresistant fraction and the R-values based on correlation analysis of Cu and Zn could be used as indicators of Cu and Zn pollution in the Malaysian aquatic ecosystem.Based on the present data,the correlation coefficients(R-values)are potential indicators of EFLE Cu and acid-reducible Cu of the sediments.The use of R-values as indicators of metal pollution is suggested and it is applicable to other heavy metal data although it should be improved in future studies.