Chemistry and evolution of Titan's atmosphere

The chemistry and evolution of Titan's atmosphere is reviewed in the light of the scientific findings from the Voyager mission. It is argued that the present N₂ atmosphere may be Titan's initial atmosphere rather than photochemically derived from an original NH₃ atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH₄ is irreversibly converted to less hydrogen rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of ～0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N₂ into hot, escaping N atoms to remove ～0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar e.u.v. energy deposition in Titan's atmosphere by an order of magnitude and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.