Thermodynamic properties of MgSiO3 ilmenite from vibrational spectra |
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Authors: | Anne M Hofmeister Eiji Ito |
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Institution: | 1. Department of Geology, University of California, 95616, Davis, CA, USA 2. Institute for Study of the Earth's Interior, Okayama University, Misasa, 682-02, Tottori-ken, Japan
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Abstract: | Unpolarized infrared (IR) reflectance spectra for MgSiO3 ilmenite taken from a single-crystal and from a densly packed polycrystalline sample possessed all eight peaks mandated by symmetry between 337 and 850 cm?1. Polarizations were inferred from intensity differences between the two samples. IR peak positions differ by up to 250 cm?1 from recent calculations, but on average are within 11%. Heat capacity C p calculated from these data by using a Kieffer-type model are within the experimental uncertainty of calorimetric measurements from 170 to 700 K. Outside this range, calculated C p is probably accurate within a few percent, based on recent results for garnets. Calculated entropy is only slightly less accurate, giving S 0 (298.15 K) as 54.1 ±0.5 J/ mol-K, which is 10% lower than recent estimates based on phase equilibria. The slope of the phase boundary between ilmenite and perovskite is used to predict S 0 (298.15 K) of perovskite as 58.7 ±1.4 J/mol-K, which is 10% lower than previous values. |
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