Oceanic versus island arc origin of ophiolites

The silica content of basaltic rocks is an unreliable variable with which to distinguish ultramafic-mafic complexes developed at ocean ridges from those potentially formed beneath volcanic island arcs. Data from Appalachian ophiolites supports the view that silica metasomatism is responsible for the high silica content of supposed calc-alkaline basaltic rocks found in ophiolites such as Troodos, and that the high-silica (70 wt.%) leucocratic rocks associated with ophiolites are of tholeiitic rather than calc-alkaline parentage. The use of titanium as a discriminant of tectonic environment is also suspect because the titanium content of basalts associated with Appalachian ophiolites as well as those recently recovered from the Atlantic ocean floor ranges from values even lower than those typical of island arc tholeiites to values typical of abyssal tholeiites. However, the internal stratigraphy of ophiolites in both the Appalachian and Tethyan systems can only be explained on the basis of the postulate that ophiolites originate at oceanic spreading centres rather than beneath island arcs.