Syn-metamorphic gold mineralisation,Invincible Vein,NW Otago Schist,New Zealand

The Invincible Vein fills a fault zone which strikes northeast and dips steeply southeast in the lower Rees Valley, NW Otago. The vein cuts north striking foliation in lower greenschist facies Otago Schist. Structures associated with the fault zone are both brittle and ductile, and the fault zone has had a complex history of post-mineralisation reactivation. Mineralised vein material filling parts of the fault zone consist of quartz, albite, muscovite, chlorite, calcite, pyrite, arsenopyrite and minor gold. These minerals have been strained and locally recrystallised during ductile deformation. Fluid inclusion homogenisation temperatures (140–175°C) and ice melting temperatures (0 to –1°C) indicate that the mineralising fluid was low salinity, low CO₂ water with a density between 0.88 and 0.93 g/cm₃. Arsenopyrite geothermometry implies a temperature of mineralisation of 370 ± 70°C. Mineralisation pressure lay between 2 and 5 kbar. Mineralisation pressure-temperature conditions and mineralogy are essentially the same as for metamorphism of the host schist. Vein calcite oxygen isotope ratios (+12 to +15 per mil) are similar to host schist values. Carbon isotope ratios of vein calcite (– 3 to –5 per mil) are distinctly different from ratios in host schist (–7 to –10 per mil). Elevated vein Cr contents, and isotopically depleted carbon data, are consistent with some degree of equilibration with metavolcanic rocks. It is inferred that metavolcanic rocks of the underlying Aspiring Terrane were a significant source for mineralising fluid and metals. Invincible mineralisation occurred in the latter stages of metamorphism, and is the earliest recognised gold-bearing vein system in the Otago Schist.